I believe in the power, speed and “update-ability” of CSS3. Not having to load background images as structural enhancements (such as PNGs for rounded corners and gradients) can save time in production (i.e. billable hours) and loading (i.e. page speed). At our company, we've happily been using CSS3 on client websites for over a year now, and I find that implementing many of these properties right now is the most sensible way to build websites.
Until today, all of that was based on an assumption: that I can produce a pixel-perfect Web page with CSS3 quicker than I can with older image-based CSS methods, and that the CSS3 page will load faster, with a smaller overall file size and fewer HTTP requests. As a single use case experiment, I decided to design and code a Web page and add visual enhancements twice: once with CSS3, and a second time using background images sliced directly from the PSD.